Germany took the reins and pressed forward whereas Spain looked shocked and unable to respond.
The victory sends Garcia into the third round, equaling her best US Open result after finishing at that stage every year from 2016 to 2018.
Briton Adam Yates retained the yellow jersey and kept a three-second lead over Jumbo's Primoz Roglic in the overall standings.
Alaphilippe had led Yates by four seconds when the race was finished and looked to have retained the yellow jersey, but television footage showed him taking a bottle from a Deceuninck-Quick Step team support member with 17.8km to go - under the rules of cycling's world governing body UCI, riders are not allowed to take on food or drink in the final 20km of a race.
In the other two clashes of the day, Hunan Hualai beat Zhejiang Energy to remain in third place, while Shenzhen Nankeda whitewashed Jiangsu in 5-0 to clinch their second win of the season. Enditem
A source told Xinhua, they have paid 50 percents of the negotiated fees at the initial stage of the three-year circle.
Flamengo netted twice in quick succession after the restart: first with a stunning first-time effort from playmaker Everton Ribeiro and then with a cool Arrascaeta finish after a counterattack.
Despite the Bavarians having dominated the national and international stage, close competition is secured as domestic competitors such as RB Leipzig, Borussia Monchengladbach, Bayer Leverkusen and Borussia Dortmund have caught up over recent years.
At Rio de Janeiro's Olympic stadium, former Chelsea forward Salomon Kalou made his debut for Botafogo but could not inspire the hosts to victory over Coritiba.
Jumbo Team's Van Aert produced a powerful sprint in the slight uphill finish to win by half a wheel ahead of Cees Bol and Sam Bennett.
Looking at the big five European leagues, the Bundesliga is the one with the most goals per game.